The goal of the Contrails project is to help preserve and disseminate the technical record of 20th century aerospace research, highlighting in particular the research endeavors of the Illinois Tech community.

Research On Heat-Resistant Acrylate-Siloxane Elastomers

Report Number: WADC TR 54-525
Author(s): Robert P. Cox; Ralph W. Buetow; Luther L. Yaeger
Corporate Author: Bj0rksten Research Laboratories, Inc.
Laboratory: Materials Laboratory
Date of Publication: 1955-02
Pages: 60
Contract: AF 33(616)-2135
Project: 7340
Task: 73404
AD Number: AD0063963

The objective of this project was the synthesis of acrylate-siloxane elastomers with good thermal and solvent resistance. Of the many polymers investigated as gum rubber bases, vinyl triethoxy-silane-acrylonitrile, ethyl acrylate compositions were the best as measured by (1) swelling in 70-30 iso-octane-toluene and in Penola oil and (2) weight loss and flexibility after heating in air at 350 F. The addition of either dibutyl phosphite or polychlorotrifluoro ethylene powder (Kel F) to these gum rubbers generally maintained their flexibility in air at 350 F. for 250 to 1000 hours. As a reinforcing filler to provide good tensile strength. carbon black (Philblack O) was superior to other fillers tested. Trimene Base was effective as a vulcanization accelerator throughout this work. The vinyl triethoxysilane-ethyl acrylate gum rubbers could be vulcanized without additives through the formation of cross-linkages. Cross-linking probably took place through adjacent >SiOH groups formed in emulsion polymerization.

Download this report

(PDF, 5.16 MB, 60 pages)

Other options for obtaining this report

Via the Defense Technical Information Center (DTIC):
A record for this report, and possibly a full-image download of the report, exists at DTIC

Via National Technical Information Service:
The NTIS Order Number for this report is: AD063963
This report may have been digitized and made freely available for public download, or made publicly available for purchase by the National Technical Information Service through their online database, the National Technical Reports Library

Indications of Public Availability
No digital image of an index entry indicating public availability is currently available
There has been no verification of an indication of public availability from an inside cover statement