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Vaporization of Compounds and Alloys at High Temperatures: On The Existance of Gaseous Sulphides Of The Transition Elements

Report Number: WADD TR 60-782 Part IV
Author: Colin, R.
Author: Jeunehomme, M.
Author: Goldfinger, P.
Corporate Author: Universite Libre de Bruxelles, Brussels, Belgium
Laboratory: Directorate of Materials and Processes
Date of Publication: 1962-05
Pages: 10
Contract: AF 61(052)-225
Project: 7350
Task: 735001
AD Number: AD0278829

Thermodynamic considerations permit us to predict the mode of vaporization of transition element sulphides. MnS is the only clear case where the gaseous sulphide molecule has an appreciable concentration in the saturated vapor. This is confirmed by a mass spectrometric investigation which gave the measurement dissociation energy (MnS) = 65 ± 5 Kcal/mole.

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